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合成了聚马来酸6-(4-辛氧基偶氮苯氧基)-1-己酯(PMAN-OAB),并以其为质子给体,4-(4-庚氧基苯甲酰氧基)-苯乙烯基吡啶(7SZ)为质子受体,研究了两者复合前后的液晶行为,结果表明,PMAN-OAB在液晶态时是以羧酸二聚体形式存在的,其倾角为39.3°,7SZ含量在40%~90%范围内的复合物液晶范围比7SZ和PMAN-OAB的宽。
Synthesis of 6- (4-octyloxyazaphenoxy) -1-hexyl maleate (PMAN-OAB) was synthesized and used as a proton donor, 4- (4-heptyloxybenzoyl (7SZ) as proton acceptor, the liquid crystal behavior before and after recombination was studied. The results show that PMAN-OAB exists in the form of carboxylic acid dimer in the liquid crystal state with an inclination of 39.3 °, 7SZ content in the range of 40% to 90% of the composite liquid crystal range wider than 7SZ and PMAN-OAB.