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合成了1个铜配位聚合物{[Cu2(Imazameth)2(bipy)](ClO4).CH2OH.H2O}n(1,Imazameth=(+/-2-(4-异丙基-4-甲基-5-氧-2-咪唑啉-2-基)-5-甲基烟酸,又称甲基咪草烟;bipy=4,4′-联吡啶)。并对其进行了元素分析,IR,荧光性质和X射线-单晶衍射表征。晶体结构表明:配合物1属于单斜晶系,P21/c空间群并且其不对称单元中包含水和乙醇分子。配合物1是由桥联配体4,4′-联吡啶和甲基咪草烟连接成“瓦楞”形层状结构,并通过分子内N-H…O氢键和分子间O-H…O氢键拓展成三维超分子结构。配合物1有较强的荧光性质。
A copper coordination polymer {[Cu2 (Imazameth) 2 (bipy)] (ClO4) .CH2OH.H2O} n (1, Imazameth = Yl-5-methyl nicotinic acid, also known as methyl imazethapyr; bipy = 4,4’-bipyridyl) .And its elemental analysis, IR, fluorescence properties and X-ray diffraction characterization.The crystal structure shows that complex 1 belongs to monoclinic space group P21 / c and contains water and ethanol molecules in its asymmetric unit.Complex 1 is composed of bridging Ligand 4,4’-dipyridyl and imazapic are linked into a “corrugated” lamellar structure and extended into a three-dimensional supramolecular structure through intramolecular NH ... O hydrogen bonds and OH ... O hydrogen bonds between molecules Complex 1 has strong fluorescence properties.