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以SnCl4·5H2O、MnCl2·4H2O和单质硫为原料,在en溶剂中通过有机溶剂热两步合成方法制备聚合的一维硫代锡酸盐[｛Mn(en)2｝2μ-en)μ-Sn2S6)]∞.用单晶X射线衍射技术对其进行晶体结构分析,[｛Mn(en)2｝2μ-en)μ-Sn2S6)]∞晶体为三斜晶系,空间群为P-1(#2),晶胞参数为:a=9.009 7(8),b=9.773 5(5),c=10.842 1(2),α=60.379(14)°,β=67.235(16)°,γ=70.250(18)°.实验结果表明:通过两步有机溶剂热反应,硫代锡酸盐趋向形成聚合体.
The synthesized one-dimensional thiosaturated salt [{Mn (en) 2} 2μ-en) μ-n-butylsulfate was synthesized by the two-step synthesis of organic solvent in en solvent using SnCl4 · 5H2O, MnCl2 · 4H2O and elemental sulfur as raw materials. Sn2S6)] ∞. The crystal structure of [{Mn (en) 2} 2μ-en) μ-Sn2S6) ∞ crystals was determined by single crystal X-ray diffraction and the space group was P-1 (# 2) with the unit cell parameters of a = 9.009 7 (8) , b = 9.773 5 (5) , c = 10.842 1 2, α = 60.379 (14) °, ) °, γ = 70.250 (18) °. The experimental results show that thio stannate tends to form a polymer through two-step organic solvent thermal reaction.