CIDNP of Diecyl Peroxides Studies on the Kinetics of Decomposition of Diacyl Peiroxides Ⅷ in the Dec

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H CIDNP spectra recorded during the decomposition of aliphatic diacyl peroxides ((RCOO)2 R=n-C H (1),n-c5H11(2)) in ODCB in the presence of scavengers,such as I2C2H5I,(CH3)2CHI,and CH2=CHCH2 Br show multiplet effect for the scavenged products,RX(X=Br,I) and for disproportionation products,R-H.The reactionmechanism is discussed in terms of radical pair theory. H CIDNP spectra recorded during the decomposition of aliphatic diacyl peroxides ((RCOO) 2 R = nC H (1), n-c5H11 (2)) in ODCB in the presence of scavengers such as I2C2H5I, (CH3) 2CHI, and CH2 = CHCH2 Br show multiplet effect for the scavenged products, RX (X = Br, I) and for disproportionation products, RH. The reaction mechanism is discussed in terms of radical pair theory.
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