Interest in the development of inorganic polymerized coagulants is growing;however,there are only limited studies on the synthesis of polytitanium coagulants,which are expected to exhibit improved coagulation efficiency with better floc properties.This study presents the synthesis of polytitanium sulfate (PTS) for potential application in water purification,followed by characterization of PTS flocs and titanium species detection.Stable PTS solutions were successfully synthesized and standard jar tests were conducted to evaluate their coagulation efficiency.Electrospray ionization time-of-flight mass spectrometry (ESI-TOF-MS) speciation analysis revealed that a variety of mononuclear and polynuclear complexes were formed in PTS solution,indicating the polymeric nature of the synthesized coagulant.Floc characteristics were studied through on-line monitoring of floc size using a laser diffraction particle size analyzer.Results showed that PTS had a comparable or in some cases even higher organic matter and particulate removal efficiency than Ti(SO4)2.The effluent pH after PTS coagulation significantly improved toward desirable values closer to neutral pH.Properties of flocs formed by PTS were significantly improved in terms of floc size,growth rate and structure.This study showed that PTS could be an efficient and promising coagulant for water purification,with the additional benefit that its coagulated sludge can be used to recover valuable TiO2 nanoparticles for various commercial applications.