前文报道了LaCl_315-冠-5配合物的电子结构和分子构型,并对其电子结合能的化学位移做了理论分析。文献中关于硝酸稀土冠醚配合物的分子构型已有若干报道,但对于氯化稀土冠醚配合物,直到本工作完成时才有一篇关于GdCl_318-冠-6分子结构的文章问世,至于氯化稀土冠醚配合物光电子能谱(XPS)的研究工作至今未见报道。我们已合成出一系列 The electronic structures and molecular configurations of LaCl_315-crown-5 complexes have been reported previously, and the chemical shifts of their electron-binding energies have been theoretically analyzed. There have been several reports in the literature about the molecular configuration of rare earth crown ether complexes, but for the rare earth crown ether complexes, there was only one article about the molecular structure of GdCl_318-crown-6 until the completion of this work. Rare earth crown ether complex photoelectron spectroscopy (XPS) research has so far not been reported. We have synthesized a series