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1,1—三氯环丙烷类化合物与萘钠反应是产生高张力环卡宾的一种新方法,用环己烯卡宾截捕剂可得到相应的卡宾加成物,本文报道了这一反应的实验结果,并讨论了该反应的可能机理。
The reaction of 1,1-trichlorocyclopropane with sodium naphthalene is a new method to generate high-tension cyclocarbene. The corresponding carbene adduct can be obtained with cyclohexenecarbene arrestant. The reaction of Experimental results, and discussed the possible mechanism of the reaction.