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合成了一种新型金属杂冠醚配合物[Mn6(4-amashz)6(DMF)6].12DMF,并用X射线衍射法对其结构进行了表征.研究了该化合物修饰金电极催化氧还原的性质,结果表明,该化合物具有平面碟状结构,对在碱性溶液中的氧有显著的催化还原作用.
A new type of metal complex ether compound [Mn6 (4-amashz) 6 (DMF) 6] 12 DMF has been synthesized and its structure has been characterized by X-ray diffraction. The results show that the compound has a flat disk-like structure, a significant catalytic reduction of oxygen in alkaline solution.