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The title complex crystallizes in the triclinic system, space group P1 with a=16.9568(5), b=18.8631(6), c=24.1640(8), α=100.110(1), β=92^330(1), γ=113.368(1)°, V=7602.54(4)~3, D_c=3.002 g/cm~3, F(000)=5893, M_r=6245.25, μ(Mo Kα)=5.010mm~-1, Z=2 and final R=0.0722 and wR=0^1960 for 16015 observed reflections with I≥2σ(I). The Gd(Ⅲ) ion is coordinated by nine oxygen atoms, forming a distorted mono-capped square antiprism, while the Mo(Ⅵ) ions have their different coordination numbers such as 4,5 and 6 with different configurations such as tetrahedron, square pyramid and octahedron, respectively.
The title complex crystallizes in the triclinic system with space group P1 with a = 16.9568 (5), b = 18.8631 (6), c = 24.1640 8, α = 100.110 1, γ = 113.368 (1) °, V = 7602.54 (4) ~ 3, D_c = 3.002 g / cm 3, F 000 = 5893, M_r = 6245.25, -1, Z = 2 and final R = 0.0722 and wR = 0 ^ 1960 for 16015 observed reflections with I≥2σ (I). The Gd (III) ion is coordinated by nine oxygen atoms, forming a distorted mono- capped square antiprism, while the Mo (Ⅵ) ions have their different coordination numbers such as 4,5 and 6 with different configurations such as tetrahedron, square pyramid and octahedron, respectively.