A series of Ce-promoted Mn-Na2WO4/SiO2 catalysts were prepared by incipient wetness impregnation method, and their catalytic performance for oxidative coupling of methane (OCM) was investigated at atmospheric pressure in a micro-quartz-tube reactor. The catalysts were characterized by X-ray diffraction (XRD), temperature program reduction (TPR) and BET surface area. Ce promoter increased surface area and Na2WO4 species dispersion, which enriched the amount of the surface species. In addition, Ce promoter increased the Na/W species reduction, but the reduction peak shifted to higher temperature. Stability test of 5wt%Ce catalyst indicated suitable performance and stability. The selectivity and yield of C2+ hydrocarbons after 50 h operation reached 65.5% and 19.6%, respectively, at 840 ℃ over 5wt%Ce-2wt%Mn-5wt%Na2WO4/SiO2 catalyst. A series of Ce-promoted Mn-Na2WO4 / SiO2 catalysts were prepared by incipient wetness impregnation method, and their catalytic performance for oxidative coupling of methane (OCM) was investigated at atmospheric pressure in a micro-quartz-tube reactor. by X-ray diffraction (TPR) and BET surface area. Ce promoter increased surface area and Na2WO4 species dispersion, which enriched the amount of the surface species. In addition, Ce promoter increased the Na / W species The selectivity and yield of C2 + hydrocarbons after 50 h operation reached 65.5% and 19.6%, respectively, at 840 ° C over 5 wt% Ce-2wt% Mn-5wt% Na2WO4 / SiO2 catalyst.