用瓶中造船法将 5,1 0 ,1 5,2 0 -四羟基苯基卟啉醋酸钴组装在 Si-MCM-4 1中 .通过 ICP元素分析、DTA差热分析及 XRD、EPR、XPS、UV-Vis光谱等对组装前后样品的含量、热稳定性、醋酸钴与 5,1 0 ,1 5,2 0 -四羟基苯基卟啉的配位情况、钴卟啉配合物在分子筛中的水热稳定性进行了研究 .结果表明 ,醋酸钴与5,1 0 ,1 5,2 0 -四羟基苯基卟啉完全能在 Si-MCM-4 1中进行配位 ,配合物在 Si-MCM-4 1中具有良好的水热稳定性及热稳定性 The 5,1 0,1 5,2 0 -tetrahydroxyphenylporphyrin cobalt acetate was assembled in Si-MCM-4 1 by the shipbuilding method in bottle.It was analyzed by ICP, DTA and XRD, EPR, XPS , UV-Vis spectra and other samples before and after assembly content, thermal stability, cobalt acetate and 5,1 0,1 5,2 0 - tetrahydroxyphenyl porphyrin coordination, cobalt porphyrin complexes in the molecular sieve The results show that cobalt acetate and 5,1 0,1 5,2 0 -tetrahydroxyphenyl porphyrin can fully coordinate in Si-MCM-4 1, -MCM-4 1 has good hydrothermal stability and thermal stability