Three sulfonyl aliphatic amines [(R2SO2)2NR1 , viz.: compound 1, in which R1 =Me, and R2 =Ph; compound 2, in which R1=n-Bu, and R2 =CF3 ; and compound 3, in which R1 =C8H17 , and R2 =CF3], have been synthesized and employed as internal electron donors (IED) for the preparation of Ziegler-Natta catalysts for the polymerization of propylene. The contents of Ti, H and C in these catalysts have been determined by elemental analysis and UV-vis spectrophotometry. The effect of the structure and dosage of the electron donor, the Al/Ti ratio and the polymerization temperature on the catalyst performance has been studied. Under optimized conditions, the catalyst with a highest activity yielded polypropylene with high isotacticity in the absence of external electron donors. In which R1 = n-Bu, and R2 = CF3; and compound 3, in which R1 (III) = C8H17, and R2 = CF3], have been synthesized and employed as internal electron donors (IED) for the preparation of Ziegler-Natta catalysts for the polymerization of propylene. The contents of Ti, H and C in these catalysts have been determined by The effect of the structure and dosage of the electron donor, the Al / Ti ratio and the polymerization temperature on the catalyst performance has been studied. Under optimized conditions, the catalyst with a highest activity yielded polypropylene with high isotacticity in the absence of external electron donors.