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Two novel complexes, namely {[Cd(AIP)(4,4?-bpy)]·1.3DMF}n(1) and [Cd(AIP)(2,2?- bpy)]n(2), have been synthesized through solvothermal reaction(H2AIP = 5-aminoisophthalic acid, 2,2?-bpy = 2,2?-bipyridine, 4,4?-bpy = 4,4?-bipyridine, and DMF = N,N?-dimethylformamide) and structurally determined by single-crystal X-ray diffraction. Complex 1 shows a three-dimensional(3D) layer-pillar framework with rectangular channels, while complex 2 displays a two-dimensional(2D) wave net architecture. Furthermore, 1 and 2 were characterized by elemental analysis, infrared spectra(IR), thermal gravimetric analyses(TGA) and fluorescence measurements. The luminescent properties of 1 dispersed in various organic solvents have been investigated systematically, demonstrating high selectivity for acetone via the fluorescence quenching effect.
Two novel complexes, namely, [Cd (AIP) (4,4? -bpy)] 1.3DMF} n (1) and [Cd (AIP) (2,2? - bpy)] n synthesized through solvothermal reaction (H2AIP = 5-aminoisophthalic acid, 2,2? -bpy = 2,2? -bipyridine, 4,4? -bpy = 4,4? -bipyridine, and DMF = N, N? -dimethylformamide) Complex 1 shows a three-dimensional (3D) layer-pillar framework with rectangular channels, while complex 2 displays a two-dimensional (2D) wave net architecture. were characterized by elemental analysis, infrared spectra (IR), thermal gravimetric analyzes (TGA) and fluorescence measurements. The luminescent properties of 1 dispersed in various organic solvents have been characterized systematically, demonstrating high selectivity for acetone via the fluorescence quenching effect.