合成了三种与咪唑配体键合的新型载体，并通过其与四苯基卟啉铁和卟啉锰配位得到了改性的负载金属卟啉催化剂。讨论了它们在催化氧化环己烷反应中的稳定性、活性等，结果表明配位负载方式明显提高了金属卟啉的稳定性，其中硅胶配位负载锰卟啉还具有较高的活性。 Three novel imidazoles ligand-binding carriers were synthesized and the supported metalloporphyrins were modified by coordination with tetraphenylporphyrin and manganese porphyrin. Their stability and activity in cyclohexane catalyzed oxidation were discussed. The results showed that the coordination loading method obviously improved the stability of metalloporphyrins, and the silica gel supported manganese porphyrin also had higher activity.