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本文合成了一个复杂的单核配合物 [Co(H2 dmg) 2 Cl2 ]3 ·[Co(H2 dmg) 2 Cl(OH) ]·[Co(Hdmg) (phen) ]·(H2 O) 4(H2 dmg =dimethylglyoxime,phen=1,10 Phenanthroline)。通过X射线衍射技术获得其单晶结构。在单晶结构中 ,每五个单核钴 (II)的配位结构形成一个重复单元 ,是一个较为复杂的单晶。其空间群为P 1,晶胞参数为a=1.3738nm ;b =1.4 396nm ;c =1.86 5 6nm。本文中我们将讨论该化合物的分子结构及相关光谱性质。
In this paper, a complex mononuclear complex [Co (H2dmg) 2Cl2] 3 · [Co (H2dmg) 2Cl (OH)] · [Co (Hdmg) (phen)] · (H2O) 4 H2 dmg = dimethylglyoxime, phen = 1,10 Phenanthroline). Its single crystal structure was obtained by X-ray diffraction. In the single crystal structure, every five mononuclear cobalt (II) coordination structure to form a repeating unit, is a more complex single crystal. The space group P 1, unit cell parameters a = 1.3738nm; b = 1.4396nm; c = 1.8665nm. In this article, we will discuss the molecular structure of the compound and related spectral properties.