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过渡金属羰基化合物是石油化学工业中广泛应用的一类催化剂。对于其催化机制的关心已激起人们对其光物理,光化学和反应动力学等方面的研究兴趣。本文报道在Fe(CO)_5分子束条件下用强紫外激光进行的多光子电离和解离动力学研究。
Transition metal carbonyls are a widely used class of catalysts in the petrochemical industry. Concern over its catalytic mechanism has aroused people’s interest in photophysics, photochemistry and reaction kinetics. In this paper, we report the multiphoton ionization and dissociation kinetics of intense UV laser beams under Fe (CO) _5 molecular beam.