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采用Keggin型多酸为无机单元,以刚性铁基配合物[Fe(phen)_2(H_2O)]作为修饰的组分,设计合成出具有新型超分子结构的无机-有机杂化晶态材料[Fe(phen)_2(H_2O)]_2(NaPMo_4~VMo_8~(VI)O_(40))](phen=1,10-Phenanthroline),该化合物属于三斜晶系,晶胞参数为a=10.947(5)?,b=13.366(5)?,c=13.687(5)?,α=69.148(5)°,β=71.387(5)°,γ=78.449(5)°,V=1765.1(12)?~3。通过单晶X-射线,对该晶态材料结构进行了分析,分析结果表明该晶态杂化材料是一种新颖的二维超分子层结构。
Using Keggin type polyacid as inorganic element and rigid iron-based complex [Fe (phen) _2 (H_2O)] as modified components, a novel supramolecular hybrid inorganic-organic hybrid material [Fe (phen) _2 (H_2O)] _2 (NaPMo_4 ~ VMo_8 ~ (VI) O_ (40))] (phen = 1,10-Phenanthroline) belongs to triclinic system with unit cell parameters of a = 10.947 ) ?, b = 13.366 (5) ?, c = 13.687 ?,? = 69.148 ?,? = 71.387 ?,? = 78.449? ~ 3. The structure of the crystalline material was analyzed by single crystal X-ray. The results show that the crystalline hybrid material is a novel two-dimensional supramolecular layer structure.