【摘 要】
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Recently,we have reported the reaction of butadiene-and isoprene(tricarbonyl)iron,in which the olefin ligand is a straight chain or branched chain conjugated d
【出 处】
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Acta Chimica Sinica(English Edition)
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Recently,we have reported the reaction of butadiene-and isoprene(tricarbonyl)iron,in which the olefin ligand is a straight chain or branched chain conjugated diene,with nucleo-phile aryllithium at low temperature and followed by subsequent alkylation with Et_3OBF_4to give a series of novel isomerized butadiene-and isoprene(dicarbonyl)[ethoxy(aryl)carbene]-iron complexes respectively.The structure of these complexes showed that the bondingmodes of central metal atom and olefin ligands are quite unique.Now we choose,as starting
Recently, we have reported the reaction of butadiene-and isoprene (tricarbonyl) iron, in which the olefin ligand is a straight chain or branched chain conjugated diene, with nucleo-phile aryllithium at low temperature and followed by subsequent alkylation with Et_3OBF_4to give a series of novel isomerized butadiene-and isoprene (dicarbonyl) [ethoxy (aryl) carbene] -iron complexes respectively. The structure of these complexes showed that the bonding atoms of central metal atom and olefin ligands are quite unique. Now we choose, as starting
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