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在N,N-二甲基甲酰胺(DMF)中,RE(NO3)3·4dmso(RE=Sm,Gd)与对叔丁基杯[6]芳烃(H6L=C66H84O6)反应,合成了两种新的稀土固体配合物,通过元素分析、红外光谱、紫外光谱和摩尔电导等实验进行了表征,确定了配合物组成为[RE(H4L)(DMF)4(OH)]·H6L.
RE (NO3) 3 · 4dmso (RE = Sm, Gd) was reacted with p-tert-butyl calix [6] arene (H6L = C66H84O6) in N, N-dimethylformamide The new rare earth solid complexes were characterized by means of elemental analysis, IR spectra, UV spectra and molar conductance. The complexes were identified as [RE (H4L) (DMF) 4 (OH)] H6L.