ω-氯、溴、碘代酮与亚磷三元酯的反应,在文献中己有系统的研究和报导。1955年А.Н.Пудовик系统地研究了ω-卤代酮与亚磷酸三乙酯的反应,他发现卤素的性质和反应温度对重排反应有很大的影响。卤素的电负性愈大和反应温度愈低,则有利于发生帕尔叩(W.perkow)重排,反之则容易起阿尔布卓夫(А.Е.Арбузов)重排。关于氟代酮与 The reaction of ω-chlorine, bromine and iodoketone with phosphorous tri-ester has been systematically studied and reported in the literature. 1955 А.Н.Пудовик systematically studied the reaction of ω-haloketones with triethylphosphite. He found that the nature of the halogen and the reaction temperature have a great influence on the rearrangement reaction. The greater the electronegativity of the halogen and the lower the reaction temperature are, it is in favor of the W. perkow rearrangement, which in turn can easily lead to the rearrangement by А.Е.Арбузов. About fluorinated ketone and