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通过在Cu/ZnO/Al2O3催化剂上CO2+H2、CO+H2和(CO/CO2)+H2催化反应动力学研究,对合成甲醇动力学和反应机理进行了细致分析,提出合成甲醇的反应机理,解释了在(CO/CO2)+H2合成甲醇过程中少量CO2的作用及合成甲醇的直接碳源.
The catalytic kinetics of the synthesis of methanol over Cu / ZnO / Al2O3 catalyst was studied by kinetics of CO2 + H2, CO + H2 and (CO / CO2) + H2. The reaction mechanism of methanol synthesis was presented. / CO2) + H2 in the role of a small amount of CO2 in the synthesis of methanol and the direct carbon source for the synthesis of methanol.