Shaped silver nanoparticles with sphere, wire and dendrite were prepared by sonoelectrochemical deposition from an aqueous solution of AgNO3 in the presence of ethylenediaminetetraacetic acid disodium salt (EDTA) and polyvi- nylpyrrolidone (PVP). The diameter of spherical silver particles was about 30 nm. The diameter of the silver nanowires was also about 30 nm and the length was 200-900 nm. The dendrites were synthesized with the concentration of silver solution increasing. Silver nanoparticles were characterized by transmission electron microscope (TEM), X-ray powder diffraction (XRD), scanning probe microscope (SPM) and UV-vis absorption spectrum. XRD patterns revealed that silver particles were of face-centered cubic structure. UV-vis absorption spectra indicated that different morphology and size of silver par- ticles could influence the optical properties. Shaped silver nanoparticles with sphere, wire and dendrite were prepared by sonoelectrochemical deposition from an aqueous solution of AgNO3 in the presence of ethylenediaminetetraacetic acid disodium salt (EDTA) and polyvi- nylpyrrolidone (PVP). The diameter of spherical silver particles was about 30 nm. The diameter of the silver nanowires was also about 30 nm and the length was 200-900 nm. The dendrites were synthesized with the concentration of silver solution increasing. Silver nanoparticles were characterized by transmission electron microscope (TEM), X-ray powder diffraction ( XRD patterns revealed that silver particles were of face-centered cubic structure. UV-vis absorption spectra showed that different morphology and size of silver par- ticles could influence the optical properties.