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The reaction of PtCl2(PPh3)2 with closo-[B10H10]2- in t-BuOH under reflux (70 h) unexpectedly afforded the nido 11-vertex platinaborane [(PPh3)2PtB10H10-9,10-(H0.7Cl0.3)2] 1, which was characterized by single-crystal X-ray diffraction study. Crystallograp