When the stagnation temperature of a perfect gas increases, the specific heat ratio does not remain constant any more, and start to vary with this temperature. The gas remains perfect, its state equation remains always valid, except it will name in more calorically im-perfect gas or gas at High Temperature. The goal of this work is to trace the profiles of the supersonic Minimum Length Nozzle with centered expansion when the stagnation temperature is taken into account, lower than the threshold of dissociation of the molecules and to have for each exit Mach number several nozzles shapes by changing the value of the temperature. The method of characteristics is used with a new form of the Prandtl Meyer function at high temperature. The resolution of the obtained equations is done by the second order of finite differences method by using the predictor corrector algorithm. A study on the error given by the perfect gas model com-pared to our model is presented. The comparison is made with a calorically perfect gas for goal to give a limit of application of this model. The application is for the air. When the stagnation temperature of a perfect gas increases, the specific heat ratio does not remain constant any more, and start to vary with this temperature. The gas remains perfect, its state equation remains always valid, except it will name in more calorically im- perfect gas or gas at High Temperature. The goal of this work is to trace the profiles of the supersonic Minimum Length Nozzle with centered expansion when the stagnation temperature is taken into account, lower than the threshold of dissociation of the molecules and to have for each each exit Mach number several nozzles shapes by changing the value of the temperature. The method of characteristics is used with a new form of the Prandtl Meyer function at high temperature. The resolution of the obtained equations is done by the second order of finite differences method by using the predictor corrector algorithm. A study on the error given by the perfect gas model com-pared to our model is presented. The comparison is made with a calorically perfect gas for goal to give a limit of application of this model. The application is for the air.