Existing form and effect of zirconium in pure Mg,Mg-Yb,and Mg-Zn-Yb alloys

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The existing form and grain refining effects of small zirconium addition in pure Mg, Mg-Yb and Mg-Zn binary alloys, and Mg-Zn-Yb ternary alloy (ZK60-Yb) were investigated. The results show that Zr element exists mainly in single and cluster particles of pure α-Zr or Zn-Zr compounds inside grains and at grain boundaries. Only the particles located in the interior of grains can act as the nucleus for α-Mg growth and effectively promote the formation of fine equiaxed grains. The broken and dispersed Zr-rich particles produced during the hot extrusion process can form nebulous banded structure in which these fine particles may act as obstacles to dislocation motion in wrought magnesium alloys. The existing form and grain refining effects of small zirconium addition in pure Mg, Mg-Yb and Mg-Zn binary alloys, and Mg-Zn-Yb ternary alloy (ZK60-Yb) were investigated. Only and particles located in the interior of grains can act as the nucleus for α-Mg growth and effectively promote the formation of fine equiaxed grains. The broken and dispersed Zr-rich particles produced during the hot extrusion process can form nebulous banded structure in which these fine particles may act as obstacles to dislocation motion in wrought magnesium alloys.
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