The isotherms of original AC (activated carbon) and photocatalysts (TiO_2-AC) calcined at 500℃ for phe-nol were measured. The results showed a reversible adsorption of phenol onto both kinds of particles at 25 ℃, and could be fitted well to the Freundlich adsorption equation for the dilute solution. Five oxidation processes, namely O_3, O_3/UV, O_3/UV/AC, O_2/UV/TiO_2 and O_3/UV/TiO_2, for phenol degradation in fluidized bed were evaluated and compared, and the photocatalytic ozonation was found to give the highest phenol conversion because of the combined actions of homogenous ozonation in the liquid phase, heterogeneous ozonation on the surface of the catalyst support, i.e. activated carbon, and heterogeneous photocatalytic oxidation on the TiO_2 catalyst surface. With the simplified kinetic model, photolytic ozonation was con-firmed to predominantly take place on the particle surface in comparison with the heterogeneous and homogeneous photolytic ozonation. Additionally, the heterogeneous photocatalytic oxidation constant was found to be enhanced by 3.73 times in photocatlaytic ozonation process with ozone as the scavenger compared to the photocatalytic oxidation process with oxygen as the scavenger.