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合成了４种新型对称三唑水杨醛Ｓｃｈｉｆ碱的铜配合物［ＣｕＬ１Ｃｌ２］（Ⅰ）和三核配合物［Ｃｕ３（Ｌ２－Ｌ４）２Ｃｌ４］·ｎＨ２Ｏ（Ⅱ～Ⅳ），其中Ｌ１，Ｌ２，Ｌ３和Ｌ４分别为４－氨基－１，２，４－三唑、４－氨基－３，５－二甲基－１，２，４－三唑、４－氨基－３，５－二乙基－１，２，４－三唑和４－氨基－３，５－二羟甲基－１，２，４－三唑的水杨醛Ｓｃｈｉｆｆ碱．经元素分析、电导、红外光谱、热重分析、电子光谱、ＥＳＲ和变温磁化率表征，该类配合物为畸变四方构型．配合物Ⅱ的变温磁化率表明，铜离子间存在弱的反铁磁相互作用，Ｊ＝－１８．９ｃｍ－１，ｇ＝２．０８，Ｆ＝２．７×１０－３．配合物对Ｂ细胞增殖有抑制作用．
Copper complexes [CuL1Cl2] (Ⅰ) and trinuclear complexes [Cu3 (L2-L4) 2Cl4] · nH2O (Ⅱ ~ Ⅳ) were synthesized by four novel Schiff bases, L3 and L4 are 4-amino-1,2,4-triazole, 4-amino-3,5-dimethyl-1,2,4-triazole, 4-amino-3,5-diethyl -1,2,4-triazole and 4-amino-3,5-dimethylol-1,2,4-triazole. By elemental analysis, conductivity, infrared spectroscopy, thermogravimetric analysis, electron spectroscopy, ESR and temperature-dependent magnetic susceptibility, these complexes are distorted tetragonal configuration. The temperature-dependent magnetic susceptibility of complex II shows that there is a weak antiferromagnetic interaction between copper ions, J = -18.9cm-1, g = 2.08 and F = 2.7 × 10-3. The complex can inhibit the proliferation of B cells.