Templating Synthesis and Luminescent Properties of SrAl_2O_4∶Eu, Dy Phosphor Derived from A Mesoporo

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:lyk_csdn
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Long-lasting SrAl2O4∶Eu, Dy phosphor was successfully prepared from a mesoporous precursor. The precursor was synthesized by templating method using nonionic Polyethylene Oxide (PEO) as surfactants, which was proved by TG-DTG, X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM) analysis. The analysis results indicated that regular cylindrical-to-hexagonal shaped pores with several nanometers were obtained. The structure and morphology of the SrAl2O4∶Eu, Dy phosphor by templating method was characterized by XRD and Scanning Electron Microscopy (SEM). The XRD results showed that a pure SrAl2O4 phase formed at 900 ℃ by templating method. The SEM morphologies of the obtained phosphors prepared by templating synthesis were uniform and porous multicrystalline with average diameter size of 5 μm. The broad-band UV-excited SrAl2O4∶Eu, Dy phosphor derived from a mosoporous precursor was observed at λmax=515 nm due to the transitions from the 4f65d1 to the 4f7 configurations of Eu2+ ion. The main excitation and emission intensity of the phosphor with this method were stronger than that obtained by solid state reaction method. And the obtained long-lasting phosphor with this method revealed a better afterglow compared to the phosphor prepared through solid state reaction method. The precursor was synthesized by templating method using nonionic Polyethylene Oxide (PEO) as surfactants, which was proved by TG-DTG, X-Ray Diffraction (XRD) and The analysis results indicated that regular cylindrical-to-hexagonal shaped pores with several nanometers were obtained. The structure and morphology of the SrAl 2 O 4: Eu, Dy phosphor by templating method was characterized by XRD and Scanning Electron Microscopy (SEM). The XRD results showed that pure SrAl2O4 phase formed at 900 ° C by templating method. The SEM morphologies of the phosph phosphor prepared by templating synthesis were uniform and porous multicrystalline with average diameter size of 5 μm. The broad-band UV -excited SrAl2O4: Eu, Dy phosphor derived from a mosoporous precursor was observed at λmax = 515 nm due to the transitions from the 4f65d1 to the 4f7 configurati The main excitation and emission intensity of the phosphor with this method were stronger than that obtained by solid state reaction method. And the obtained long-lasting phosphor with this method revealed a better afterglow compared to the phosphor prepared through solid state reaction method.
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