Ni-based Ni-Fe-B-Si-Ta bulk metallic glasses

来源 :Science China(Physics,Mechanics & Astronomy) | 被引量 : 0次 | 上传用户:jiajia0321
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The glass-forming ability and properties of Ni-based Ni-Fe-B-Si-Ta bulk metallic glasses are explored in this work. The alloy compositions are determined by using a combination of the cluster line approach, the multi-alloying strategy and the substitutions of similar elements. Bulk metallic glasses with diameters of 3 mm take shape at compositions formulated under the clus- ter-plus-glue-atom model [M9B]B~[(Ni1-xFex)7.71(Si0.66Ta0.34)1.29B]B0.94=(Ni1-xFex)70.5B17.7Si7.8Ta4, x=0.35–0.45, where the bracketed part is the cluster and the unbracketed part is the glue atoms. These alloys exhibit good magnetic properties. The maximum Is is found in the (Ni0.55Fe0.45)70.5B17.7Si7.8Ta4 alloy which reaches 0.51 T, with its Hc as low as 8.5 A/m. Interestingly, these alloys display dual glass transitions at (Ni0.65Fe0.35)70.5B17.7Si7.8Ta4, (Ni0.60Fe0.4)70.5B17.7Si7.8Ta4 and (Ni0.55Fe0.45)70.5B17.7- Si7.8Ta4 as unveiled by Temperature-Modulated Differential Scanning Calorimetry. The glass-forming ability and properties of Ni-based Ni-Fe-B-Si-Ta bulk metallic glasses are explored in this work. The alloy compositions are using a combination of the cluster line approach, the multi-alloying strategy and The substitutions of similar elements. Bulk metallic glasses with diameters of 3 mm take shape at compositions formulated under the clustering plus-glue-atom model [M9B] B ~ [(Ni1-xFex) 7.71 (Si0.66Ta0.34) 1.29B] B0.94 = (Ni1-xFex) 70.5B17.7Si7.8Ta4, x = 0.35-0.45, where the bracketed part is the cluster and the unbracketed part is the glue atoms. These alloys exhibit good magnetic properties. The maximum Interestingly, these alloys display dual glass transitions at (Ni0.65Fe0.35). It is found that the (Ni0.55Fe0.45) 70.5B17.7Si7.8Ta4 alloy which reaches 0.51 T, with its Hc as low as 8.5 A / m. ) 70.5B17.7Si7.8Ta4, (Ni0.60Fe0.4) 70.5B17.7Si7.8Ta4 and (Ni0.55Fe0.45) 70.5B17.7-Si7.8Ta4 as unveiled by Temperature-Modulated Differential Scanning Calorimetry.
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