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利用新方法合成了一类新型的钼铜硫异校双金属配合物Mo(t-BuNC)_4(μ-t-BuS)_2CuX,3X=Cl,4X=Br,5X=I,其中3和5为未知的新化合物;研究了它们的IR,~1H NMR特征;考察了它们与生体内钼铜对抗作用的可能关系。
A new type of Mo (t-BuNC) _4 (μ-t-BuS) _2CuX, 3X = Cl, 4X = Br and 5X = I was synthesized by the new method. As unknown new compounds; their IR, ~ 1H NMR characteristics were studied; and their possible relationship with the antagonism of molybdenum and copper in vivo was investigated.