本文阐明了“活性元件组装”设想在过渡金属硫桥原子簇合理合成方面的基本思想,指出合理合成过渡金属硫桥原子簇时,具有孤对电子的配位不饱和的硫原子所起的重要作用。总结了硫原子在化合物中的配位构型及其与组装活性的关系,并例举六种类型的“元件组装”,清楚表明了“元件组装”是合成过渡金属硫桥原子簇的合理途径,并指出了“元件组装”设想在含其他桥原子的过渡金属原子簇中的可能应用。 In this paper, the basic idea of ​​“active component assembly” in the rational synthesis of transition metal sulfur bridge clusters is illustrated. It is pointed out that the importance of coordinating unsaturated sulfur atoms with lone pairs of electrons in the rational synthesis of transition metal sulfur bridge clusters effect. Summarizes the sulfur atom in the compound coordination structure and its relationship with the assembly activity and cites six types of “component assembly” clearly shows that “component assembly” is a reasonable way to synthesize transition metal sulfur bridge clusters , And pointed out the possible application of “component assembly” in transition metal clusters with other bridge atoms.