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合成和表征了4种新型配合物[Cu_2(TPHA)(NO_2-Phen)_1](ClO_1)_2·H_2O、[Cu_2(TPHA)(Me-bpy)_1](ClO_1)_2、[Mn_2(TPHA)(NO_2-Phen)_1](ClO_1)_2·2H_2O和[Mn_2(TPHA)(Me-bpy)_1](ClO_1)_2(TPHA:对苯二甲酸根阴离子;NO_2-Phen:5-硝基-1,10-菲绕啉;Me-bpy:4,4’-二甲基-2,2’-联吡啶).测定了配合物的变温磁化率,并求出了交换积分J分别为-5.04、-6.52、-0.68及-0.73cm~(-1).
Four novel complexes [Cu_2 (TPHA) (NO_2-Phen) _1] (ClO_1) _2 · H_2O, [Cu_2 (TPHA) (Me_bpy) _1] (ClO_1) _2 and [Mn_2 (TPHA) (NO_2-Phen) _1] (ClO_1) _2 · 2H_2O and [Mn_2 (TPHA) (Me_bpy) _1] (ClO_1) _2 (TPHA: terephthalate anion; , 10-phenanthroline; Me-bpy: 4,4’-dimethyl-2,2’-bipyridine) .The magnetic susceptibility of the complex was measured and the exchange integral J was calculated to be -5.04, -6.52, -0.68 and -0.73 cm -1.