Study on VUV and UV Excitation Spectrum of GdVO_4∶Eu~( 3+)

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:cashcumt
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The photoluminescence spectra and excitation spectra in the vacuum ultraviolet (VUV) and ultraviolet (UV) spectra region of GdVO 4∶Eu 3+ were reported. The excitation and emission spectra indicate that GdVO 4∶Eu 3+ is a highly efficient phosphor for the excitation in the VUV and UV spectrum region. The excitation band in the VUV and UV spectrum region of 60~350 nm consists mainly of the absorption of host, which has obvious absorption of 4f n-1 5d of Eu 3+ and Gd 3+ . In GdVO 4∶Eu 3+ , there is the energy transfer: VO 4 3- →Eu 3+ , Gd 3+ →Eu 3+ and Gd 3+ →VO 4 3- →Eu 3+ . Through the last two procedures, maybe the quantum cutting of Gd 3+ -Eu 3+ occurs. The photoluminescence spectra and excitation spectra in the vacuum ultraviolet (UVUV) and ultraviolet (UV) spectra region of GdVO 4Eu 3+ were reported. The excitation and emission spectra indicate that GdVO 4Eu 3+ is a highly efficient phosphor for the The excitation band in the VUV and UV spectrum regions of 60-350 nm consists mainly of the absorption of host, which has a significant absorption of 4f n-1 5d of Eu 3+ and Gd 3+ . In GdVO 4Eu 3+, there is the energy transfer: VO 4 3- → Eu 3+, Gd 3+ → Eu 3+ and Gd 3+ → VO 4 3- → Eu 3+. Through the last two procedures , maybe the quantum cutting of Gd 3+ -Eu 3+ occurs.
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