Solvothermal-induced construction of ultra-tiny Fe2O3 nanoparticles/graphene hydrogels as binder-fre

来源 :稀有金属(英文版) | 被引量 : 0次 | 上传用户:laner12
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Three-dimensional (3D) ultra-tiny Fe2O3 nanoparticles/graphene hydrogels were prepared using a facile and efficient solvothermal reaction,by which the phase of iron oxide,particle size and the morphology of hydrogels can be precisely controlled by simply adjusting the solvothermal reaction time.Accordingly,the effect of the microstructures of hydrogels on electrochemical per-formance was systematically studied.It was found that Fe2O3/rGO-50 hydrogels (with a solvothermal reaction time of 50 min) possessed a desirable crystallinity,suit-able particle size,decent porous structure,large specific surface area and high electrical conductivity,thus exhibiting a superior electrochemical performance as bin-der-free anode of supercapacitors:a large potential range of 1.15 V,an ultrahigh specific capacitance of 1090 F·g-1 at a current density of 2 A·g-1 and excellent rate capability(531 F·g-1 at 10 A·g-1).The rational design and system-atic research of electrode materials will provide new lights for the preparation of advanced electrochemical energy storage devices.
其他文献
Hydrogen is considered to be an ideal safe and clean energy source,which can be produced by water splitting.The high overpotential of hydrogen evolution reaction (HER) is one of the bottleneck issues for the practical application of water splitting,where
本文以《Excel数据图表》一课为例,从四个方面阐述了以技术支持信息技术教学的实施过程,旨在技术助力教学方式的改变,提升教学效率.这四个方面分别是:采用微课助力教学重难点的解决;在线考试工具助力课堂教学效果检测;思维导图助力知识总结、归纳;云存储工具助力课堂延伸.
Two-dimensional (2D) transition metal dichalcogenides (TMDCs) have attracted growing interest regarding their potential applications in next-generation electronic and optoelectronic devices.Owing to their atomic thickness and tunable bandgap,they exhibit
Combining metal to form metal phosphide is a promising strategy to address the fast capacity decay of P rooted from its low electronic conductivity and large vol-ume changes upon cycling.Cu3P,which possesses a high theoretical gravimetric and volumetric c
Metallic nanoparticles (NPs) are a class of important materials with widespread applications due to their chem-ical stability and high photothermal conversion efficiency.
期刊
Electrocatalytic CO2 reduction reaction(CO2RR) converts CO2 into valuable chemical fuels,which can effectively alleviate global warming and energy crisis.However,limited by its slow reaction rate and low product selectivity,it is urgent to design efficien
Today,nanocrystals enclosed by high-index facets (HIFs) are attracting widely attentions of researchers due to their tremendous potential in the field of catalysis,especially in electrocatalysis,such as electro-oxidation of small organic molecule (such as
In this study,the LiFePO4 cathode was syn-thesized by the ionic thermal method using the deep eutectic mixture of tetramethyl ammonium chloride and urea.The synthetic conditions were systematically inves-tigated by orthogonal experiments,which indicate th
The practical application of the lithium anode in lithium metal batteries (LMBs) has been hindered by the uncontrollable growth of lithium dendrite and the high volumetric change during cycling.Herein,the in situ formed three-dimensional (3D) lithium-boro
The self-corrosion,electrochemical and dis-charge behavior of commercial purity Al anode via Mn modification in Al-air battery was studied by the hydrogen evolution,weight loss,electrical conductivity,electro-chemical and discharge tests.Results show that