论文部分内容阅读
(Ph4As)2[Mn2(SC3H8S)4] was obtained from the reaction of MnCl2-4H2O,Na2(1,2-pdt)(1,2-H2pdt=CH3CH(SH)CH2SH),and Ph4AsCl.C80H64As2Mn2S8, Mr =1301.41,orthorhombic,Pbca; a=10.854(2), b =22.562(6), c =24.545(6)A; V=6010.8A3;Z =4,Dc=1.44g/cm3. The centrosymmetic anion of title compound is a dimer of (Mn(pdt)2]- bridged by one sulfur atom each of the two bridging pdt2-, The atom Mo(Ⅲ) is in a distorted trigonal bipyramidal geometry.
(Ph4As) 2 [Mn2 (SC3H8S) 4] was obtained from the reaction of MnCl2-4H2O, Na2 (1,2-pdt) (1,2-H2pdt = CH3CH (SH) CH2SH), and Ph4AsCl.C80H64As2Mn2S8, Mr = 1301.41, orthorhombic, Pbca; a = 10.854 (2), b = 22.562 (6), c = 24.545 (6) A; V = 6010.8A3; Z = 4, Dc = 1.44 g / cm3. The centrosymmetic anion of title compound is a dimer of (Mn (pdt) 2] - bridged by one sulfur atom each of the two bridging pdt2-, The atom Mo (III) is in a distorted trigonal bipyramidal geometry.