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The title compound, [Mn(4,4’-bpy)1.5(H2O)3](ClO4)·(4,4’-bpy)(L)·H2O(1), where L=2,4,6-trimethylbenzoic acid, was synthesized and its crystal structure was determined by X-ray diffraction analysis. The crystal is of triclinic, space group P1 with a=2.929 9(6) nm, b=1.036 4(2) nm, c=8.222 0(1) nm, α=105.300(2)°, β=97.495(2)°, γ=91.118(2)°, V=1.884 0(4) nm3, Z=2, Mr=780.10, Dc=1.375 g·cm-3, μ=0.483 mm-1, F(000)=812, R=0.055 4, wR=0.135 2. The Mn atoms are octahedrally coordinated by three N atoms of three 4,4’-bipyridine ligands and three O atoms of water. The complex shows a one-dimensional chain structure bridged by water and 4,4’-bipyridine molecules. CCDC: 615707.
The title compound, [Mn (4,4’-bpy) 1.5 (H2O) 3] (ClO4) · (4,4’-bpy) (L) · H2O trimethylbenzoic acid, was synthesized and its crystal structure was determined by X-ray diffraction analysis. The crystal is of triclinic, space group P1 with a = 2.929 9 (6) nm, b = 1.036 4 (1) nm, α = 105.300 (2) °, β = 97.495 (2) °, γ = 91.118 (2) °, V = 1.884 4 nm3, Z = 2, Mr = 780.10, Dc = 1.375 g · Cm -3, μ = 0.483 mm -1, F (000) = 812, R = 0.055 4, w R = 0.135 2. The Mn atoms are octahedrally coordinated by three N atoms of three 4,4’-bipyridine ligands and three O atoms of water. The complex shows a one-dimensional chain structure bridged by water and 4,4’-bipyridine molecules. CCDC: 615707.