RFe7Mn4Ti化合物的结构和磁性(R=Y,Tb,Dy,Ho,Er)

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研究了Mn部分替代RFe11Ti中的Fe对化合物结构和磁性的影响. 利用真空电弧熔炼和真空热处理制备RFe7Mn4Ti(R=Y, Tb, Dy, Ho和Er)化合物样品. 室温粉末样品的X射线衍射和热磁曲线测量表明:所有这些化合物都具有单ThMn12型结构,且具有良好的单相性,其晶格常数和单胞体积随着稀土元素的不同而变化. 在DyFe7Mn4Ti和HoFe7Mn4Ti化合物的热磁曲线上出现了明显的补偿特征,补偿温度分别约为123*!K和90*!K.同时给出了这些化合物的居里温度、饱和磁化强度及每单位分子式的饱和磁矩.
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