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报道了锰卟啉系列化合物被ＰｈＩＯ氧化开环的反应动力学和取代基效应对反应的影响规律．研究结果表明：单锰卟啉被ＰｈＩＯ氧化反应在动力学上为一级反应，且反应动力学常数ｋ与取代基特性常数σ之间存在线性关系．
The influence of reaction kinetics and substituent effect on the reaction of manganese porphyrin series compounds by PhIO oxidation was reported. The results show that the oxidation reaction of Mono-manganese porphyrin is first-order kinetics, and there is a linear relationship between the reaction kinetic constant k and the substituent constant σ.