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根据色谱热力学理论,建立高效液相色谱中富勒烯的分离因子与碳数之间的定量相关模型,用实测数据进行了成功检验。按所提模型推算 C_(60)~C_(96)在 5种固定相上不同流动相下的分离因子与实验值相比,总的平均相对误差为2.9%。
According to the chromatographic thermodynamics theory, the quantitative correlation model between the separation factor and carbon number of fullerene in high performance liquid chromatography was established, and the data were successfully tested with the measured data. According to the proposed model, the separation factor of C_ (60) ~ C_ (96) under different mobile phases on five stationary phases was 2.9% compared with the experimental data.