Metal-enhanced fluorescence of graphene oxide by palladium nanoparticles in the blue-green part of t

来源 :Chinese Physics B | 被引量 : 0次 | 上传用户:s574751142
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Graphene oxide(GO) has a wide fluorescence bandwidth,which makes it a prospective candidate for numerous applications.For many of these applications,the fluorescence yield of GO should be further increased.The sp~2-hybridized carbons in GO confine the π-electrons.Radiative recombination of electron-hole pairs in such sp~2 clusters is the source of fluorescence in this material.Palladium nanoparticles are good catalysts for sp~2 bond formations.We report on the preparation of GO,palladium nanoparticles and their nanocomposites in two different solvents.It is shown that palladium nanoparticles can considerably enhance the intrinsic fluorescence of GO in the blue-green part of the visible light spectrum.Fluorescence enhancement has been attributed to the catalytic role of palladium nanoparticles in increasing the number of sp2 bonds of GO with the molecules of the surrounding media.It is shown that palladium nanoparticles could be the nanoparticle of choice for fluorescence enhancement of GO because of their catalytic role in sp2 bond formation. Graphene oxide (GO) has a wide fluorescence bandwidth, which makes it a prospective candidate for numerous applications. For many of these applications, the fluorescence yield of GO should be further increased. The sp ~ 2-hybridized carbons in GO confine the π- electrons.Radiative recombination of electron-hole pairs in such sp ~ 2 clusters is the source of fluorescence in this material. Palladium nanoparticles are good catalysts for sp ~ 2 bond formations. We report on the preparation of GO, palladium nanoparticles and their nanocomposites in Two different solvents. It is shown that palladium nanoparticles can considerably enhance the intrinsic fluorescence of GO in the blue-green part of the visible light spectrum. Fluorescence enhancement has been attributed to the catalytic role of palladium nanoparticles in increasing the number of sp2 bonds of GO with the molecules of the surrounding media. It is shown that the palladium nanoparticles could be the nanoparticle of choice for fluorescence enhancement o f GO because of their catalytic role in sp2 bond formation.
其他文献
In this paper, the synthesis of a novel polyoxovanadiumborate [Li(H2O)3]3 [V12 B18 O48 (OH)12 (OH)] · (H2 O)s by hydrotherrnal method.FTIR, 2D FTIR and UV-Vis absorption spectroscopy were em ployed to
This account gives an overview of our recent work in the area of conjugated azomethines derived from 2-aminothiophenes.It will be presented that mild reaction c
Pattern formations in an Oregonator model with superdiffusion are studied in two-dimensional(2D) numerical simulations. Stability analyses are performed by appl
The objective of the present work was to assess the efficacy and complications of the use of the lotus petal flap in the vulvoperineal reconstruction among fema
由中国中药行业协会、中国医药商业协会、国药励展共同举办的2012中国中药行业年度峰会是我国中药行业发展的一个展示,在一定程度上反映了我国中药产业的现状,预示着产业发展
Based on the completely parametric crystal-field model, the energy level parameters, including free-ion parameters and crystal-field parameters, obtained by fit
美国一项新的研究发现 ,有抗氧化作用的维生素可抵消降胆固醇剂 (烟酸及辛伐他汀 )的主要功效。与单用降胆固醇制剂相比 ,将抗氧化维生素类制剂与降胆固醇药并用 ,仅可少量增
A series of novel N-(3-furan-2-yl-1-phenyl-1H-pyrazol-5-yl) amides derivatives were designed and synthesized. Their structures were confirmed by ~1H NMR, ~(13)
利用5-甲基-3-吡唑甲酸,分别与CoCl2·6H2O和Ni(NO3)2·6H2O反应,得到了配合物[M(MPA)2(H2O)2](1:M=Co;2:M=Ni)(HMPA=5-甲基-3-吡唑甲酸)。用元素分析、红外光谱、X-单晶衍射
本发明涉及一种醋酸赖氨酸的制备方法。具体包括以下步骤:1)以盐酸赖氨酸为原料经过离子交换柱得到L-赖氨酸液;2)将L-赖氨酸液与冰醋酸反应得到醋酸赖氨酸水溶液;