【摘 要】
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The aggregation of dansyl chloride (DNS-Cl) in acetone has been studied in detail by steady-state fluorescence techniques. It has been demonstrated that DNS-Cl
【出 处】
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Chinese Journal of Chemistry
论文部分内容阅读
The aggregation of dansyl chloride (DNS-Cl) in acetone has been studied in detail by steady-state fluorescence techniques. It has been demonstrated that DNS-Cl is stable in acetone during purification and aggregation study processes. The aggregates are not solvolyzed in acetone, and do not take part in any chemical reactions either. It has been found that DNS-Cl tends to aggregate even when its concentration is much lower than its solubility in acetone. The aggregation is reversible, and both the aggregation and the deaggregation are very slow processes. Introduction of SDS has a positive effect upon the formation and stabilization of the aggregates.
The aggregation of dansyl chloride (DNS-Cl) in acetone has been studied in detail by steady-state fluorescence techniques. It has been been demonstrated that DNS-Cl is stable in acetone during purification and aggregation study processes. The aggregates are not solvolyzed in acetone , and do not take part in any chemical reactions either. It has been found that DNS-Cl tends to aggregate even when its concentration is much lower than its solubility in acetone. The aggregation is reversible, and both the aggregation and the deaggregation are very slow processes. Introduction of SDS has a positive effect upon the formation and stabilization of the aggregates.
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