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以顺-4-环己烯-1,2-二羧酸(chedc)、3,5-二(4-吡啶基)-1,2,4-三氮唑(4,4’-bpt)、六水合硝酸钴为原料,通过室温条件下自然挥发得到一个单核Co(II)的配合物[Co(chedc)(4,4’-bpt)_2(H_2O)_3]NO_3·H_2O(1),其结构经IR、元素分析、X-射线单晶衍射进行表征.晶体属单斜晶系,空间群P21/c,晶胞参数a=1.198(2)nm,b=1.361(3)nm,c=2.202(4)nm,β=92.65(3)°,V=3.584(12)nm3,Z=4,Dc=1.499 g·cm-3,F(000)=1676,R1=0.0627,ωR2=0.1190.
(4-pyridyl) -1,2,4-triazole (4,4’-bpt), cis-4-cyclohexene- Co (chedc) (4,4’-bpt) _2 (H_2O) _3] NO_3 · H_2O (1) was obtained by natural evaporation of the cobalt nitrate hexahydrate at room temperature under natural conditions. Its structure was characterized by IR, elemental analysis and X-ray single crystal diffraction. The crystal belongs to the monoclinic system with the space group P21 / c, the unit cell parameters a = 1.198 (2) nm and b = 1.361 = 2.202 (4) nm, β = 92.65 (3) °, V = 3.584 (12) nm3, Z = 4, Dc = 1.499 g · cm -3, F (000) = 1676, R1 = .