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采用水热法合成了一个新的分子式为[Co(mbix)2(H2O)2]n·5n H2O·n NIPH的金属-有机配合物(mbix=1,3-双(咪唑基-1-甲基)苯,H2NIPH=5-硝基间苯二甲酸),并对其进行了元素分析、红外光谱测定和X-射线单晶衍射的结构解析.该配合物(C36H35Co N9O13)属于三斜晶系,空间群为P1,晶体学数据:a=9.3843(6),b=10.5905(6),c=10.9456(7),α=82.1180(10)°,β=84.5760(10)°,γ=71.8050(10)°,V=1022.12(11)3,Mr=860.66,Dc=1.398g/cm3,μ(Mo Kα)=0.494mm-1,F(000)=445,Z=1.直接法解析原子位置的结果显示:R=0.0593,w R=0.0966.该配合物具有一维链状结构.
A novel metal-organic complex of [Co (mbix) 2 (H2O) 2] n · 5nH2O · n NIPH was synthesized by hydrothermal method (mbix = 1,3-bis ) And H2NIPH = 5-nitroisophthalic acid) were synthesized and characterized by elemental analysis, infrared spectroscopy and X-ray single crystal diffraction analysis.The complex (C36H35Co N9O13) belongs to triclinic system , Space group P1, crystallographic data: a = 9.3843 (6) , b = 10.5905 (6) , c = 10.9456 7, α = 82.1180 (10) ° and β = 84.5760 (10) γ = 71.8050 (10) °, V = 1022.12 (11) 3, Mr = 860.66, Dc = 1.398g / cm3, μ (Mo Kα) = 0.494mm-1, F (000) = 445, Z = The results of the direct method for analyzing the position of the atom showed that: R = 0.0593, w R = 0.0966. The complex has one-dimensional chain structure.