本文研究某些冠醚化合物的XPS内壳谱、振起伴峰及XPS价带谱。分析了它们的内壳谱特征,指出它们的振起伴峰是由于分子内电荷转移的结果。同时探讨了它们的XPS价带谱中由具有最低结合能峰位所确定的“电离势”与分子中苯环上不同取代基效应间的关系。 In this paper, some of the crown ether compounds XPS within the shell, vibration with the peak and XPS valence band spectrum. Their inner shell spectral features were analyzed, pointing out that their vibrational peak was due to the intramolecular charge transfer. The relationship between the “ionization potential” determined by the lowest binding energy peak in their XPS valence bands and the effect of different substituents on the benzene ring in the molecule was also discussed.