N-doped carbon nanofibers arrays as advanced electrodes for supercapacitors

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The advancement ofsupercapacitors largely relies on the innovation of electrode materials with high-rate performance and ultra-long cycling stability.In this work,unique N-doped nanofibers on carbon cloth (N-CNFs/CC) are prepared by an electrodeposition-annealing method for application in supercapacitors.The as-prepared N-doped nanofibers (N-CNFs) show diameters of 100-150 nm and cross-link with each other forming porous conductive network.Due to enhanced conductivity and reinforced structural stability,the N-CNFs/CC arrays are demonstrated with better electrochemical performance than CNFs/CC counterpart,including higher specific capacitance (195.2 F g-1 at a current density of 2.5 A g-1),excellent rate capability(80.5.% capacity retention as the rate increases from 2.5-20 A g-1) and good cycling stability (99.5.%retention after 10,000 cycles).These reinforced electrochemical properties are attributed to N-doped conductive architecture with faster ion/electron transfer paths and more active sites.Our findings may offer a new way for construction of advanced high-rate electrodes for energy storage.
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