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采用Envi-carb/NH2复合柱净化,GC/MS法检测,对提取条件、净化条件和检测条件充分优化后,建立了卷烟主流烟气总粒相物中4种氨基甲酸酯类农药(久效威、甲奈威、克百威和抗蚜威)含量的快速分析方法.该方法的线性范围为0.01 ～ 10.0 mg/L,相关系数(R)大于0.9966,日内、日间相对标准偏差(RSD)均小于6.97％,检测限(LOD)均为10 μg/L,样品的加标回收率均大于90.20％～92.80％.方法用于卷烟主流烟气总粒相物中氨基甲酸酯类农药含量的测定,结果令人满意.“,”A rapid analysis method based on solid-phase extraction (SPE) and gas chromatographymass spectrometry (GC/MS) was established to analyze four carbamate pesticides in mainstream cigarette smoke.The quality control problem of this analytical method was discussed particularly.The linear range of this method was 0.01～ 10.0 mg/L.The linear correlation coefficient (R) was higher than 0.9966.The intra-day and inter-day relative standard deviations (RSD) were less than 6.97％.And the recovery values ranging from 90.20％ to 92.80％.The method was successfully used on the determination of carbamate pesticides in mainstream cigarette smoke.