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以水滑石焙烧而成的Mg-Al复合氧化物(Mg(A1)O)固体碱负载磺化酞菁钴(CoPcTS)双功能催化剂催化1-辛硫醇氧化反应,具有与含10%NaOH的传统催化体系相似的催化性能,能有效地将1-辛硫醇氧化为二硫化合物.催化剂在循环使用时,活性下降,可能与CoPcTS氧化中心聚集有关.
Hydrotalcite calcined Mg-Al composite oxide (Mg (Al) O) solid alkali-supported sulfonated phthalocyanine cobalt (CoPcTS) bifunctional catalyst for catalytic oxidation of 1-octanethiol, with 10% NaOH The catalytic performance of the traditional catalytic system can effectively oxidize 1-octanethiol to the disulfide compound. When the catalyst is recycled, the activity decreases, which may be related to the aggregation of the CoPcTS oxidation center.