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This article describes two kinds of model oil samples made of a benzothiophene/octane mixture and a 2-me- thylthiophene/octane mixture. Furthermore, this paper investigates the oxidative desulfurization selectivity and reaction efficiency when Ce4+ compound and H2O2 having identical electron equivalent weight were used as oxidants. The test re- sults showed that the two kinds of oxidants were more effective to remove benzothiophene in the model oil samples. For oxidative desulfurization of 2-methylthiophene, Ce4+ compound was obviously superior than H2O2. This paper by means of quantum chemistry analyses elaborates the complex formed between Ce4+ species and 2-methylthiophene and FT-IR spec- trograms of model oil samples before and after oxidation by Ce4+ compound and H2O2, respectively. The results demonstrat- ed that Ce4+ compound could remove sulfur compounds not only through oxidation reaction but also through complexation reaction.
This paper describes two kinds of model oil samples made of a benzothiophene / octane mixture and a 2-me-thylthiophene / octane mixture. Furthermore, this paper investigates the oxidative desulfurization selectivity and reaction efficiency when Ce4 + compound and H2O2 has identical electron equivalent weight were Used as oxidants. The test re- sults showed that the two kinds of oxidants were more effective to remove benzothiophene in the model oil samples. For oxidative desulfurization of 2-methylthiophene, Ce4 + compound was obviously superior to H2O2. This paper by means of quantum of chemistry analyzes elaborates the complex formed between Ce4 + species and 2-methylthiophene and FT-IR spec- trograms of model oil samples before and after oxidation by Ce4 + compound and H2O2, respectively. The results demonstrat- ed that Ce4 + compound could remove sulfur compounds not only through oxidation reaction but also through complexation reaction.