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根据Bunte盐[S-烃基(或芳基)硫代硫酸盐]在大部分反应中是烃硫基上的硫原子被(立木)核性试剂所进攻,作者希望Bunte盐能够在中性或酸性溶液中根据下式与硫脲作用而得到混合的过硫化物阳离子(Ⅰ): 但结果却得到了高产率的二烃基过硫化物,二氧化硫和硫酸;作者由此研究了这一反应的发生过程,发现在大部分的情况下,在硫脲存在时,由Bunte盐合成过硫化物的作用可以用下列的式子说明:
Depending on the Bunte salt [S-alkyl (or aryl) thiosulfate], in most reactions the sulfur atom on the hydrocarbon thio group is attacked by the (ribonucleic acid) nuclear reagent and the authors hope that the Bunte salt will work in neutral or acidic The solution was treated with thiourea to give a mixed persulfate cation (I) according to the formula: but the result was high diamino-sulfide, sulfur dioxide and sulfuric acid; the authors therefore investigated the course of this reaction , It was found that in most cases the effect of the synthesis of peroxides from the Bunte salt in the presence of thiourea can be illustrated by the following formula: