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研究了Ni(naph)2─Al(i—Bu)3─BF3·ROH催化体系引发了二烯聚合的动力学行为,得到了不同条件下的各动力学参数、表现活化能和频率因子,从动力学角度研究了分子量调控机理。
The kinetic behavior of diene polymerization initiated by Ni (naph) 2-Al (i-Bu) 3-BF 3 · ROH catalyst system was studied. The kinetic parameters under different conditions were obtained, and the activation energy and frequency factor were obtained. Kinetic study of molecular weight regulation mechanism.